Chemistry and Mechanism of Art Materials

Chapter 1 Essential Concepts

Chemical Bonding, Solubility, Properties of Solids,

Hard and Soft Acids and Bases

Oxidation-Reduction

Chemical Reaction Mechanisms

Experimental Methods Used to Characterize Works of Art

Chapter 2 Preparation of Inorganic Pigments

Introduction

Black Pigments

Antimony Black

Carbon Blacks

Cobalt Black

Iron Oxide, Magnetite

Manganese Black

Blue Pigments

Azurite

Cerulean Blue

Egyptian Blue

Prussian Blue

Smalt

Ultramarine

Verdigris

Brown Pigments

Iron (III) Oxide Pigments

Lead Dioxide

Green Pigments

Chromium Oxide

Hydrated Chromium Oxide, Viridian

Malachite, see Azurite

Paris Green

Verdigris

Red Pigments

?-Cinnabar and Vermilion

Red Lead

Iron (III) Oxide, Hematite

?-Realgar, see Orpiment

Violet Pigments

Pigment Violet 14

White Pigments

Antimony White

Barium White

Lithopone

Titanium White

White Lead

Zinc White

Zinc Sulfide

Yellow Pigments

Bismuth Vanadate

Cadmium Pigments

Cobalt Yellow

Iron (III) Oxide

Lead Chromate

Lead Tin Yellow type I

Lead Tin Yellow type II

Lead Monoxide, Litharge and Massicot

Lead Tin Antimonate, Naples Yellow

Orpiment

Titanium Yellow

Chapter 3 Silica, Silicates and Aluminosilicates

Introduction

Silica

Silicates

Pigment-Silicate Interactions

Pottery Glazes

Aluminosilicates

Chapter 4 Discoloration Stories

Introduction

Smalt

Red Lead

Realgar

Cinnabar

Hematite

Chrome Yellow

Silverpoint

Cadmium Yellow

Blackening of Pigments by H2S

Ultramarine

Azurite and Malachite

Medieval Pigments

Chapter 5 Toxicology of Art Materials

Introduction

Organics

Methylene Chloride

Carbon Tetrachloride

Trichloroethylene

n-Hexane

N-Methylpyrrolidone

Diisocyanates

Alcohols, Glycols and Glycol Ethers

Mineral Spirits

Inorganics

Lead

Zinc, Cadmium and Mercury Familial Properties

Cadmium

Mercury

Silver

Arsenic

Chromium

Chapter 6 Ageing of Oil Paint

Oxidative Degradation of Oil Binder

Metal Soap formation

Chapter 7 Ageing of Wall Paintings

Secco and Fresco methods

Reversal of Sulfation

Deposition of Water Soluble Salts

Degradation of Oil Binder

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• Artes: temas gerais
• Ciências da vida: temas gerais
• Ciência ambiental, engenharia e tecnologia
• Museus e museologia
• Pintura e obras de pintura
• Química inorgânica
• Guias de arte, museus, locais históricos e galerias
• Estilos de arte não definido por data
• Ciência dos materiais
• Química industrial

American Chemical Society;Chrome Yellow;Inorganic artists' pigments;Oil Binder;synthesis;Gogh;discoloration;Vincent Van Gogh;toxicology;Metal Soaps;aging of oil paint;Red Lead;mechanism;Cadmium Yellow;XANES;Linseed Oil;FTIR Spectrum;XANES Region;Calcium Oxalate;Calcium Oxalate Dihydrate;Wall Paintings;Ir Spectra;FTIR Image;IARC Group;Elsevier Masson SAS;Glyceride Esters;Van Den Berg;Fe III;Oxide Anion;Metal Oxalates;IR Spectrum